Temperature differences among the cells in a battery pack significantly aggravate the unbalanced discharging phenomenon between the cells, although the overall output voltage and discharge capacity of the battery pack may be negligibly affected.
When a battery is discharged and the discharge process approaches the voltage turn point of the battery pack, the discharge current through the cell at a higher temperature begins to decrease significantly. After the Depth of Discharge (DOD) reaches approximately 90%, the discharge current of the cell at a higher temperature rises again.
For a battery pack with a parallel combination, the capacity loss rate increases as the temperature difference between the cells increases. Higher operating temperatures of the cells lead to a higher capacity loss rate of the battery pack. For the battery pack, the temperature affects its capacity loss rate by increasing as the temperature difference among the cells widens.
Temperature differences among the cells in a battery pack can lead to significant differences in internal resistance. The passage mentions that the larger the temperature differences, the more the difference in internal resistance between cells. However, the total internal resistance of the battery pack changes little, with a 10 °C temperature difference resulting in approximately 10% lower total internal resistance compared to 5 °C.
Temperature differences among the cells in a battery pack can lead to unbalanced discharging and aging. This results in slightly increased output voltage and discharging capacity for the battery pack. These increments are more pronounced in the case of lower ambient temperatures. This phenomenon is explained by the dependence of the cell internal resistance on the temperature.
The temperature differences among cells in a battery pack must be well controlled (≤5 °C) to minimize the unbalanced discharging and aging between cells. This is especially important as the ambient temperature increases.
Cold Temperature Charge / Discharge
Degradation of the cathode at low temperature is mainly due to the decreased Li + diffusion coefficient and high charge transfer resistance caused by low kinetics, leading to significantly increased polarization. These problems impede the (de)lithiation process, incurring certain energy and capacity loss
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How uneven temperatures in battery packs affect …
Uneven temperatures within a battery pack can negatively affect its performance, longevity, and efficiency. Having all the cells at almost the same operating temperature is necessary for properly charging and …