Al metal is one of the most attractive anode materials in post-lithium batteries in view of its numerous merits, such as low cost and high Earth abundance, as well as high charge density and gravimetric/volumetric capacities, compared with Na, K, and Zn (Fig. 1a and Supplementary Table 1) 10, 21, 24, 25.
3.5. Lithium-ion battery performance of copper–aluminum composite foils Here, we used 6 μm copper–aluminum composite foil and 6 μm commercial electrolytic copper foil as the anode collector of lithium-ion battery. Graphite was used as the anode material and made into a slurry, which was then coated on the two collectors respectively.
At the same time, the raw material price of aluminum is much lower than that of copper, which can lead to a reduction in the raw material cost of the battery. Therefore, copper–aluminum composite foils are expected to be applied in the energy storage field that prioritizes high energy density and lightweight over excellent cycling performance.
After reconnecting the composite foil to the negative pole of the DC power supply, the copper layer was deposited using the reduction reaction of copper ions in the electroplated copper solution under the current, thus preparing the copper–aluminum composite foils.
The copper–aluminum composite foil produced using this method is expected to be utilized as the anode collector in lithium-ion batteries for aircrafts. This will help us achieve the goal of creating lightweight and high-added-value products.
Chemical plating and electroplating can be used to prepare ultra-thin copper–aluminum composite foils. The process is shorter than the traditional aluminum-based copper plating process. Preparation of transition layers by electroplating tin can form beneficial rivet structures.
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The expansion of capacity and the rapid growth in the lithium battery foil industry has led to increased pressure on the supply side. The processing fee of lithium battery copper foil to fall owing to poor terminal automobile industry chain caused by the pandemic, weak demand, and the high prices of the battery-oriented raw materials.
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This energy density is comparable to that of other metal‑sulfur batteries such as sodium‑sulfur (Na S) batteries (3079 Wh L −1), magnesium‑sulfur (Mg S) batteries (3115 Wh L −1), and lithium‑sulfur (Li S) batteries (3290 Wh L −1).
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In summary, we developed a copper-on-aluminum plating process using tin plating instead of alternative zinc with a shorter time and better controllability, which effectively …
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