Owing to its high theoretical specific capacity, effective working voltage, and abundant raw materials, antimony sulfide (Sb 2 S 3) was regarded as one promising anode material for electrochemical energy conversion and …
Although the antimony based anode optimization method has been widely studied, the safety performance of the whole battery is determined by electrolyte and cathode materials, so the construction of GWh-factories, such as energy storage power stations, is still relatively difficult.
Even at 0.5 A g − 1, the optimal MXene@Sb-300 electrode also maintains highly reversible capacity of 148.43 mAh g − 1 after 1000 cycles, demonstrating the feasibility of antimony as alloying-type Zn storage material for aqueous Zn-ion batteries.
Benefiting from the zincophilic antimony seeds and 3D MXene architecture, the MXene@Sb can significantly suppress Zn dendrite and achieve a long cycling life up to 1000 h. This study demonstrates the feasibility of antimony as alloying-type Zn storage anode and provides an effective approach to suppress Zn dendrites. 1. Introduction
Recently, antimony (Sb) has been extensively researched as a promising candidate due to its high specific capacity through an alloying/dealloying process.
The theoretical capacity of antimony metal as the negative electrode of a sodium ion battery is 660 mAh/g. Currently, the energy density of lithium-ion batteries can reach up to 300 Wh kg −1.
However, the peak location does not return to pristine antimony (23.36°), which is due to the crystalline lattice change after Zn alloying/dealloying. The ex-situ XPS are also performed to detect the composition and valence evolutions at different discharge/charge states.
Owing to its high theoretical specific capacity, effective working voltage, and abundant raw materials, antimony sulfide (Sb 2 S 3) was regarded as one promising anode material for electrochemical energy conversion and …
Rechargeable aqueous zinc-based batteries (ZBBs) are attracting more and more attention for portable electronic equipment and large-scale energy storage due to their high energy density and low cost. However, further applications of ZBBs still face many challenges, including the issues of side reactions (hydrogen evolution, corrosion, and passivation) and zinc …
Antimony oxides (Sb x O y) show electrochemical reaction activity with all of lithium, sodium and potassium, and are expected to be promising anode materials for alkali metal-ion storage due to their high theoretical capacities, appropriate operating potential and excellent safety properties.
for large-scale renewable energy storage, with antimony being a primary requirement for these batteries. Photovoltaic (PV) Glass Antimony is used as a clarifying agent in solar photovoltaic (PV) glass, which can generate clean electricity thanks to the sun, potentially turning buildings into vertical power generators. 2 Antimony Price Has More Than Doubled in 2024 An extreme …
Aiming at their energy-storage applications, the significant utilizations in electrodes, separators, electrolyte and metal-protection were detailedly reviewed in lithium-ions battery, lithium...
Aiming at their energy-storage applications, the significant utilizations in electrodes, separators, electrolyte and metal-protection were detailedly reviewed in lithium …
All these results indicate the feasibility and promising prospects of antimony as alloying-type anode in aqueous Zn-metal free Zn-ion batteries. The alloying mechanism can be extended to other aqueous and non-aqueous power sources. 2.4. Electrochemical performance of MXene@Sb-300 as anodic host for Zn metal anode. The alloying-type Zn storage mechanism …
The asymmetric supercapacitor (ASC) composed of antimonene and carbon nanotubes exhibits a wide voltage window and excellent energy storage performance, …
Owing to its high theoretical specific capacity, effective working voltage, and abundant raw materials, antimony sulfide (Sb 2 S 3) was regarded as one promising anode material for electrochemical energy conversion and storage, especially regarding alkali-ion (Li +, Na +, and K +) batteries.
As a potential substitute for LIBs in energy storage devices, SIBs have attracted extensive attention because sodium is much cheaper than lithium, environmentally friendly, and SIBs show the same energy storage mechanism as LIBs (Wang et al., 2018; Cao et …
Sodium-ion batteries have been one of the most promising alternatives for lithium-ion batteries (LIBs) for large-scale energy storage systems due to cost-efficiency and rich resources of sodium.
Thanks to its abundant reserves, relatively high energy density, and low reduction potential, potassium ion batteries (PIBs) have a high potential for large-scale energy storage applications. Due to the large radius of potassium ions, most conventional anode materials undergo severe volume expansion, making it difficult to achieve stable and ...
In addition, the challenges and prospects for the future study and application of WS2/WSe2@graphene nanocomposites in electrochemical energy storage applications are proposed. In recent years, tungsten disulfide (WS2) and tungsten selenide (WSe2) have emerged as favorable electrode materials because of their high theoretical capa
For electrochemical energy storage in LIBs, application-specific demands vary: long-term high-frequency storage requires high energy density and longevity, while short-term high-frequency storage necessitates high-current charge-discharge capabilities and high-power density (Roy and Srivastava, 2015).Refer to Fig. 1 below to understand the fundamental …
In this review, the research progress of Sb 2 S 3 -based nanomaterials in the SIB field in recent years is summarized, including Sb 2 S 3, Sb 2 S 3 /carbon composites, Sb 2 S 3 /graphene composites, and Sb 2 S 3 …
Antimony is recognized by the US Department of the Interior as a critical mineral essential to US economic and national security. It is used in defense systems, renewable energy generation and storage, high-tech manufacturing, and numerous other applications. China is the world''s largest producer of antimony, controlling nearly half of global ...
In this review article, we will focus on different categories of the emerging Sb based anode materials with distinct sodium storage mechanisms including Sb, two-dimensional antimonene and antimony chalcogenide (Sb2S3 and Sb2Se3). For each part, we emphasize that the novel construction of an advanced nanostructured anode with unique structures ...
Antimony oxides (Sb x O y) show electrochemical reaction activity with all of lithium, sodium and potassium, and are expected to be promising anode materials for alkali metal-ion storage due to their high …
Developing novel anodes with outstanding fast‐charging properties is crucial for next‐generation energy storage research. Sb2S3 materials are deemed promising electrodes due to their high theoretical…
This review will give a latest overview of research progress in the design and application of electrode materials based on antimony and bismuth, and offer some value insights into their future development in sodium storage. Sodium-ion batteries (SIBs) that efficiently store electricity into chemical energy have been extensively pursued
It is found that antimony can reversibly alloy with Zn to form ZnSb phase, which enable antimony as both alloying-type Zn storage material and zincophilic nucleation seed to regulate homogeneous Zn deposition.
At present, many water resources are facing the problems of pollution. Antimony pollution is getting more and more attractive in recent years (Yao et al., 2021, Fei et al., 2017).With the development of industry, antimony-containing products are increasingly used in various fields, such as catalysts for polyester fiber production (Abbasi et al., 2019), energy …
The asymmetric supercapacitor (ASC) composed of antimonene and carbon nanotubes exhibits a wide voltage window and excellent energy storage performance, demonstrating its potential application in electrochemical energy storage.
Thanks to its abundant reserves, relatively high energy density, and low reduction potential, potassium ion batteries (PIBs) have a high potential for large-scale energy …
It is found that antimony can reversibly alloy with Zn to form ZnSb phase, which enable antimony as both alloying-type Zn storage material and zincophilic nucleation seed to …
In this review article, we will focus on different categories of the emerging Sb based anode materials with distinct sodium storage mechanisms including Sb, two …
This review will give a latest overview of research progress in the design and application of electrode materials based on antimony and bismuth, and offer some value insights into their …
Developing novel anodes with outstanding fast‐charging properties is crucial for next‐generation energy storage research. Sb2S3 materials are deemed promising …
In this review, the research progress of Sb 2 S 3 -based nanomaterials in the SIB field in recent years is summarized, including Sb 2 S 3, Sb 2 S 3 /carbon composites, Sb 2 S 3 /graphene composites, and Sb 2 S 3 /M x S y composites. Furthermore, the challenges and prospects for the development of Sb 2 S 3 -based nanomaterials are also put forward.
Another original insight in this review is that we put forward a potential application prospect for the antimony-containing waste adsorbents. The feasible future development includes the utilization of the recycled antimony-containing waste adsorbents in catalysis and energy storage, and this will provide a green and sustainable pathway for both …
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